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WebDec 19, 2013 · Alcohols, Catalysts, Ethers, Hydrocarbons, Redox reactions Abstract The thermodynamically leveraged conversion of ethers and alcohols to saturated … WebAlcohol to Triflate (Tf 2 O) Examples: Example 1 To a solution of the SM (100 g, 380 mmol) and TEA (76.8 g, 760 mmol) in DCM (1.5 L) at 0 C was added Tf2O (107 g, 380 mmol) … improvement interactive india pvt ltd

Friedel–Crafts cyclization of tertiary alcohols using bismuth(III) triflate

WebAlcohols and esters can be converted efficiently to olefins under solvent-free conditions using metal triflate catalysts. However, the conversion of ethers to alkenes requires … WebJACS1972, 94, 6190 - Stable to base and mild acid - under controlled condition is selective for 1° alcohols t-butyldimethylsilyl triflate tBuMe2Si-OTfTL1981, 22, 3455 - very reactive silylating reagent, will silylate 2° alcohols cleavage: - acid - F-(HF, nBu4NF, CsF, KF) O TBSO CO2Me OTBS HF, CH 3CN O HO CO2Me HO (70%) Webof peaks for glycosyl triflate 2a in the 1H NMR spectrum at −80 °C (Figure€1). In contrast to the previous reports by Kerns and Ye, the corresponding β-triflate was not observed under these conditions [11,19]. The small coupling constant of the anomeric proton (J = 2.1 Hz) indicates α-configuration of the anomeric triflate. improvement in taylor rule